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191124

Sigma-Aldrich

Poly(methyl vinyl ether-alt-maleic acid)

average Mw ~216,000 by LS, average Mn ~80,000, powder

Synonym(s):

Maleic acid-methyl vinyl ether copolymer, Methoxyethylene-maleic acid copolymer, Poly(maleic acid-methyl vinyl ether), Vinyl methyl ether-maleic acid copolymer

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About This Item

Linear Formula:
[CH2CH(OCH3)CH(CO2H)CH(CO2H)]n
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

powder

mol wt

average Mn ~80,000
average Mw ~216,000 by LS

pH

~2.5 (5% in H2O)

SMILES string

COC=C.OC(=O)\C=C\C(O)=O

InChI

1S/C4H4O4.C3H6O/c5-3(6)1-2-4(7)8;1-3-4-2/h1-2H,(H,5,6)(H,7,8);3H,1H2,2H3/b2-1-;

InChI key

HHEHWCIYDICHCG-ODZAUARKSA-N

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General description

Poly(methyl vinyl ether-alt-maleic acid) (PMVEMA) is a hydrophilic polymer which is biocompatible with bioadhesive properties. It is an acidic polymer that can be used to improve the stability and zeta potential of polyaniline (PANI) solution.

Application

PMVEMA can be cross-linked with cellulose whiskers for the formation of nanocomposite films for potential usage in medical and food packaging applcations. It can also be conjugated with polyethylene glycol (PEG) to form hydrogels which can be used in drug delivery systems.
Detergent builder.

Features and Benefits

Dissolves readily in water, chelates alkaline earth cations but not toxic heavy metal ions.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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A novel nanocomposite film prepared from crosslinked cellulosic whiskers
Goetz L, et al.
Carbohydrate Polymers, 75(1), 85-89 (2009)
Poly (methyl vinyl ether-alt-maleic acid)-Functionalized Porous Silicon Nanoparticles for Enhanced Stability and Cellular Internalization
Shahbazi M, et al.
Macromolecular Rapid Communications, 35(6), 624-629 (2014)
The Effect of Poly (methyl vinyl ether-alt-maleic acid) Stabilizer on the Stability of Polyaniline-Poly (methyl vinyl ether-alt-maleic acid) Dispersions
Koo CM, et al.
Journal of Colloid and Interface Science, 227(2), 316-321 (2000)
Hydrogels prepared from cross-linked nanofibrillated cellulose
Nair SS, et al.
ACS sustainable chemistry & engineering, 2(4), 772-780 (2014)

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