108871
4-Chloro-o-phenylenediamine
97%
Synonym(s):
4-Chloro-1,2-diaminobenzene
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About This Item
Linear Formula:
ClC6H3(NH2)2
CAS Number:
Molecular Weight:
142.59
Beilstein:
508472
EC Number:
MDL number:
UNSPSC Code:
12162002
eCl@ss:
39030501
PubChem Substance ID:
NACRES:
NA.23
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Assay
97%
mp
70-73 °C (lit.)
SMILES string
Nc1ccc(Cl)cc1N
InChI
1S/C6H7ClN2/c7-4-1-2-5(8)6(9)3-4/h1-3H,8-9H2
InChI key
BXIXXXYDDJVHDL-UHFFFAOYSA-N
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Application
Undergoes cyclizations and cyclocondensations to form benzimidazoles.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis, 446-446 (1992)
4-Chloro-o-phenylenediamine.
Report on carcinogens : carcinogen profiles, 10, 59-59 (2004-08-24)
Hiroshi Suzuki et al.
Mutation research, 583(2), 133-145 (2005-05-19)
We conducted simultaneous liver and peripheral blood micronucleus assays in young rats with seven rodent hepatocarcinogens-4,4'-methylenedianiline (MDA), quinoline, o-toluidine, 4-chloro-o-phenylenediamine (CPDA), dimethylnitrosamine (DMN), p-dimethylaminoazobenzene (DAB), and di(2-ethylhexyl)phthalate (DEHP)-and two mutagenic chemicals-kojic acid and methylmethanesulfonate (MMS). Quinoline, DMN, and DAB were
W Suter et al.
Mutation research, 414(1-3), 149-156 (1998-06-19)
4-Chloro-o-phenylenediamine (4-C-o-PDA) is a liver carcinogen in mice and was found to be weakly mutagenic in the liver of female Big Blue mice after short term treatment. In the present study the test compound was given subchronically in the diet
F Staedtler et al.
Mutation research, 430(1), 121-130 (1999-12-11)
The monocyclic aromatic amine 4-chloro-o-phenylenediamine (4-C-o-PDA), a known mutagen and mouse hepatocarcinogen, was tested for its in vivo mutagenic potential in the Big Blue transgenic mouse assay system. Genomic DNA was isolated from liver tissue of control and treated animals
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