39116

Tricyclazole

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Synonym(s): 5-Methyl[1,2,4]triazolo[3,4-b][1,3]benzothiazole
• Empirical Formula (Hill Notation): C₉H₇N₃S
• CAS Number: 41814-78-2
• Molecular Weight: 189.24
• Beilstein: 980261
• MDL number: MFCD00072466

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• storage temp.: 2-8°C
• SMILES string: Cc1cccc2sc3nncn3c12
• InChI: 1S/C9H7N3S/c1-6-3-2-4-7-8(6)12-5-10-11-9(12)13-7/h2-5H,1H3
• InChI key: DQJCHOQLCLEDLL-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified by ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

Tricyclazole is a systemic triazolobenzothiazole fungicide used mainly for the control of Pyricularia oryzae on rice. It prevents the fungus from penetrating the epidermis, thereby protecting the plants/and thus, protecting the plants. The compound acts by inhibiting melanization within the appressorium, causing a lack of rigidity in the appressorial wall.

As per Regulation (EC) No 1107/2009, repealing the directive 91/414/EEC, tricyclazole is not approved for use in the European Union. A maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of tricyclazole in fresh/frozen fruits, and tree nuts, in accordance with Regulation (EU) 2017/983.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.

The tricyclazole CRM may also find the following uses:

• Determination of tricyclazole content in paddy rice using sliver colloid as a substrate and pyridine as an internal standard by surface-enhanced Raman spectroscopy (SERS)
• To detect residues of tricyclazole and thiram in pear fruit extracts using SERS
• Dissipation studies of penoxsulam, tricyclazole, and profoxydim in rice paddy systems using HPLC-Diode Array Detection (DAD)
• Determination of tricyclazole residues in rice using liquid chromatography-tandem mass spectrometry (LC-MS/MS) along with the QuEChERS method of sample preparation
• Degradation of tricyclazole (TC) in an aqueous solution and real pesticide industry wastewater (RPW) by electron beam (EB) radiation

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS06
• Signal Word: Danger
• Hazard Statements: H301 - H412
• Precautionary Statements: P264 - P270 - P273 - P301 + P310 - P405 - P501
• Hazard Classifications: Acute Tox. 3 Oral - Aquatic Chronic 3
• Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable