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676845

Sigma-Aldrich

Diethyl ether

≥98.0%, ACS reagent, contains ≤2% ethanol and ≤10ppm BHT as inhibitor

Synonym(s):

Et2O, Ethoxyethane, Ether, Ethyl ether

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About This Item

Linear Formula:
(CH3CH2)2O
CAS Number:
60-29-7
Molecular Weight:
74.12
Beilstein:
1696894
EC Number:
200-467-2
MDL number:
MFCD00011646
UNSPSC Code:
12352112
PubChem Substance ID:
329760655
NACRES:
NA.07

product name

Diethyl ether, ACS reagent, ≥98.0%, contains ≤2% ethanol and ≤10ppm BHT as inhibitor

grade

ACS reagent

vapor density

2.6 (vs air)

vapor pressure

28.5 psi ( 55 °C)
8.38 psi ( 20 °C)

Assay

≥98.0%

form

liquid

autoignition temp.

320 °F

contains

≤2% ethanol and ≤10ppm BHT as inhibitor

expl. lim.

36.5 %

impurities

≤0.0002 meq/g Titr. acid
≤0.001% Carbonyl (as HCHO)
≤0.5% (water)
≤1 ppm Peroxide (as H2O2)

evapn. residue

≤0.001%

color

APHA: ≤10

refractive index

n20/D 1.3530 (lit.)

bp

34.6 °C (lit.)

mp

−116 °C (lit.)

density

0.706 g/mL at 25 °C (lit.)

SMILES string

CCOCC

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3

InChI key

RTZKZFJDLAIYFH-UHFFFAOYSA-N

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General description

Diethyl ether (also known as ethyl ether or ether) is a laboratory solvent. It is a desirable solvent for oils, fats, waxes, perfumes, dyes, resins, hydrocarbons, and gums. It is also used as fuel and to synthesize other chemical compounds. DEE is widely employed as a solvent for Grignard synthesis.

Application

Diethyl ether is used as a solvent in the 3D-printed reaction ware device for chemical synthesis.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H224,H302,H336

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019,EUH066

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

-40.0 °F - closed cup

Flash Point(C)

-40 °C - closed cup

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The solvent effect on the I⋯O halogen bonding in complexes of iodobenzene derivatives with formaldehyde has been investigated by systematically varying the substituents on the iodobenzene ring. Calculations have been performed at MP2 and DFT levels of theory, using the
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