936987

DTBPF Pd G3 ChemBeads

• Synonym(s): 1,1′-Bis(di-tert-butylphosphino)ferrocene Pd G3
• Empirical Formula (Hill Notation): C₃₉H₅₇FeNO₃P₂PdS
• Molecular Weight: 844.15
• UNSPSC Code: 12352100

Properties

• form: solid
• Quality Level: 100
• composition: , 4-6 wt. % (loading of catalyst)
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 87-150 °C ((decomposition))
• functional group: phosphine
• SMILES string: CC(P(c1cccc1)C(C)(C)C)(C)C.CC(P(c2cccc2)C(C)(C)C)(C)C.NC3=C(C4=CC=CC=C4[Pd]OS(C)(=O)=O)C=CC=C3.[Fe]
• InChI: 1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1
• InChI key: AGXLTHQKOWPGBX-UHFFFAOYSA-M

Description

General description

DTBPF Pd G3 is a versatile palladium precatalyst developed by Buchwald group. It is widely employed in various cross-coupling reactions involving the formation of C-C, C-N, C-O, C-F, C-CF₃, and C-S bonds. Precatalysts effectively generate active catalytic species for use in various reactions.

Application

For general uses, product is also available in powdered form (804975)

Features and Benefits

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Other Notes

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Safety Information

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable