D8801
2,6-Diacetylpyridine
98%
Synonym(s):
1,1′-(2,6-Pyridinediyl)diethanone, 1-(6-Acetylpyridin-2-yl)ethanone
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About This Item
Empirical Formula (Hill Notation):
C9H9NO2
CAS Number:
Molecular Weight:
163.17
Beilstein:
118286
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
mp
79-82 °C (lit.)
SMILES string
CC(=O)c1cccc(n1)C(C)=O
InChI
1S/C9H9NO2/c1-6(11)8-4-3-5-9(10-8)7(2)12/h3-5H,1-2H3
InChI key
BEZVGIHGZPLGBL-UHFFFAOYSA-N
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Application
2,6-Diacetylpyridine can be used as a starting material for the synthesis of:
- Iron and cobalt bis(imino)pyridyl complexes, catalysts for ethylene oligomerization.
- Thiosemicarbazone derivatives with potential application as anti-mycobacterial tuberculosis agent.
- Macrocyclic pentadentate nitrogen–sulphur donor ligands by [1+1] condensation with 1,2-di(o-aminophenylthio)ethane.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Oligomerisation of Ethylene by Bis (imino) pyridyliron and-cobalt Complexes.
Britovsek GJP, et al.
Chemistry?A European Journal , 6(12), 2221-2231 (2000)
Thiosemicarbazones, semicarbazones, dithiocarbazates and hydrazide/hydrazones: Anti-Mycobacterium tuberculosis activity and cytotoxicity.
Pavan FR, et al.
European Journal of Medicinal Chemistry, 45(5), 1898-1905 (2010)
Chromium (III), manganese (II), iron (III), cobalt (II), nickel (II) and copper (II) complexes with a pentadentate, 15-membered new macrocyclic ligand.
Chandra S and Gupta K
Transition Metal Chemistry, 27(2), 196-199 (2002)
Manja Kubeil et al.
ChemistryOpen, 8(5), 637-642 (2019-05-30)
A photoactivatable ruthenium(II) carbonyl complex mer,cis-[Ru(II)Cl(BisQ)(CO)2]PF62 was prepared using a tridentate bisquinoline ligand (BisQ=(2,6-diquinolin-2-yl)pyridin). Compound 2 was thoroughly characterized by standard analytical methods and single crystal X-ray diffraction. The crystal structure of the complex cation reveals a distorted octahedral geometry.
Ali Sayqal et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 242, 118711-118711 (2020-08-02)
Herein, the presented manuscript provides for an extensive spectrofluorimetric method for micro determination of silver ion. This established method based on the use of the three synthesized 2,6-disubstituted pyridine derivatives (R1, R2 and R3) through exploiting their high fluorescence emission
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