930857
Ni(bpy)Cl2
Synonym(s):
[Bipyridine]nickel(II) dichloride
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About This Item
Empirical Formula (Hill Notation):
C10H8Cl2N2Ni
CAS Number:
Molecular Weight:
285.78
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.21
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form
powder
Quality Level
greener alternative product characteristics
Catalysis
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storage temp.
−20°C
SMILES string
Cl[Ni]1([N]2=CC=CC=C2C3=CC=CC=[N]31)Cl
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General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
Ni(bpy)Cl2 is a nickel catalyst used for a variety of cross-coupling reactions.
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Product No.
Description
Pricing
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Synthesis of α-Aryl Secondary Amides via Nickel-Catalyzed Reductive Coupling of Redox-Active Esters.
Alexis L Gabbey et al.
Organic letters, 24(17), 3173-3178 (2022-04-27)
The transition-metal-catalyzed α-arylation of secondary amides remains a synthetic challenge due to the presence of a free N-H bond. We report a strategy to synthesize secondary α-aryl amides via a Ni-catalyzed reductive arylation of redox-active N-hydroxyphthalimide (NHP) esters of malonic
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