919977

Lithium bis(trifluoromethanesulfonyl)imide

anhydrous, 99.99% trace metals basis

• Synonym(s): Bis(trifluoromethane)sulfonimide lithium salt, LiNTf₂, LiTFSI, LiTf₂N, Bis(trifluoromethylsulfonyl)amine lithium salt, Lithium bistrifluoromethanesulfonimidate
• Linear Formula: CF₃SO₂NLiSO₂CF₃
• CAS Number: 90076-65-6
• Molecular Weight: 287.09
• Beilstein: 6625414
• MDL number: MFCD00210017
• UNSPSC Code: 12352111

Properties

• grade: anhydrous
• Quality Level: 200
• Assay: 99.99% trace metals basis
• greener alternative product characteristics: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• mp: 234-238 °C (lit.)
• application(s): battery manufacturing
• greener alternative category: Enabling,
• SMILES string: [Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F
• InChI: 1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
• InChI key: QSZMZKBZAYQGRS-UHFFFAOYSA-N

Description

General description

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Application

Lithium bis(trifluoromethanesulfonyl)imide can be used as:

• An additive in the development of dual-functional separator coating materials. These materials are based on covalent organic frameworks (COFs) and are specifically designed for use in high-performance lithium-selenium sulfide batteries. The Li-SeS₂ battery achieved outstanding performance in terms of energy storage and stability. It exhibited a specific capacity of 844.6 mA h g^-1 at 0.5C and a SeS₂ loading of 2 mg cm^-2.
• As an additive in the electrolyte formulation along with polyethylene oxide for the development of solid-state lithium batteries. LiTFSI enhance the ionic conductivity of the PEO-based electrolyte, which is essential for the efficient transport of lithium ions.
• As a key component in the development of a PEO/LiTFSI-coated polypropylene membrane. This membrane is designed for high-loading lithium–sulfur batteries to enhance battery performance, improve capacity, and extend cycle life.
• As a component in the electrolyte system along with TEMPOL derivatives. The incorporation of LiTFSI in the electrolyte system enhances the stability and achieves an efficiency of 6.16% in solid-state fiber dye-sensitized solar cells.

Safety Information

• Pictograms: GHS05,GHS06,GHS08
• Signal Word: Danger
• Hazard Statements: H301 + H311 - H314 - H373 - H412
• Precautionary Statements: P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral
• Target Organs: Nervous system
• Storage Class Code: 6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable