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75992

Sigma-Aldrich

Palladium on activated charcoal

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5% Pd basis

Synonym(s):

Pd/C

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About This Item

Linear Formula:
Pd
MDL number:
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

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Catalysis
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concentration

5% Pd

greener alternative category

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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Application

Palladium on activated charcoal (Pd/C) is a catalyst used in hydrogenation of alkenes, alkynes, ketones, nitriles, imines, nitro groups, aromatic and heteroaromatic systems. Pd/C also catalyzes phosphination of aryl bromides and triflates with triphenylphines to yield aryl phosphines.
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Pictograms

Flame

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of aryl phosphines by phosphination with triphenylphosphine catalyzed by palladium on charcoal.
Lai, Chi Wai et al.
Tetrahedron Letters, 42(29), 4883-4885 (2001)
Sonogashira coupling of aryl halides catalyzed by palladium on charcoal.
Novak, Zoltan et al.
The Journal of Organic Chemistry, 68(8), 3327-3329 (2003)
Palladium on Carbon.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Examination of the aromatic amination catalyzed by palladium on charcoal.
Komaromi, Anna and Novak, Zoltan
advanced synthesis and catalysis, 352(9), 1523-1532 (2010)
Examination of the aromatic amination catalyzed by palladium on charcoal.
Komaromi, Anna and Novak, Zoltan
Advanced Synthesis & Catalysis, 352(9), 1523-1532 (2010)

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