740411
Potassium azide
≥99.9% trace metals basis
Synonym(s):
Azidopotassium
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About This Item
Empirical Formula (Hill Notation):
KN3
CAS Number:
Molecular Weight:
81.12
EC Number:
UNSPSC Code:
12352125
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥99.9% trace metals basis
form
solid
mp
~300 °C (decomposition)
SMILES string
[K+].[N-]=[N+]=[N-]
InChI
1S/K.N3/c;1-3-2/q+1;-1
InChI key
TZLVRPLSVNESQC-UHFFFAOYSA-N
Application
Potassium azide can be used as a reagent to synthesize:
- 3-O-(3-Azidoopropyl)estrone from 3-O-(3-methanesulfonyloxypropoxy)estrone via nucleophilic azidation in the presence of imidazolium catalyst.
- Azido phenacyl derivatives from α-bromoacetophenone derivatives in the presence of tetrabutylammonium bromide as a catalyst.
- 1-Azido-4-fluorobenzene from potassium (4-fluorophenyl)trifluoroborate in the presence of cupric triflate as a catalyst.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Oral
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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