695718

(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

95%

• Synonym(s): (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
• Empirical Formula (Hill Notation): C₄₈H₂₉O₄P
• CAS Number: 361342-51-0
• Molecular Weight: 700.72
• UNSPSC Code: 12352005
• PubChem Substance ID: 329761763
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 95%
• form: solid
• mp: 288-292 °C (D)
• functional group: phosphate
• storage temp.: −20°C
• SMILES string: OP1(=O)Oc2c(cc3CCC=Cc3c2-c4c(O1)c(cc5ccccc45)-c6c7ccccc7cc8ccccc68)-c9c%10ccccc%10cc%11ccccc9%11
• InChI: 1S/C48H31O4P/c49-53(50)51-47-41(43-35-19-7-1-13-29(35)25-30-14-2-8-20-36(30)43)27-33-17-5-11-23-39(33)45(47)46-40-24-12-6-18-34(40)28-42(48(46)52-53)44-37-21-9-3-15-31(37)26-32-16-4-10-22-38(32)44/h1-5,7-17,19-28H,6,18H2,(H,49,50)
• InChI key: SZKDXDJLUYHXLW-UHFFFAOYSA-N

Description

Application

Catalyst used in asymmetric direct alkylation of α-diazoester via C-H bond cleavage.

Catalysts used in enantioselective condensation/amine addition reactions

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves