659274
Potassium allyltrifluoroborate
95%
Synonym(s):
Potassium trifluoro(prop-2-enyl)borate
About This Item
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Assay
95%
form
solid
mp
>300 °C
SMILES string
[K+].F[B-](F)(F)CC=C
InChI
1S/C3H5BF3.K/c1-2-3-4(5,6)7;/h2H,1,3H2;/q-1;+1
InChI key
TVPZAMJXLCDMIT-UHFFFAOYSA-N
Application
- Catalytic allylboration
- Stereoselective nucleophilic addition
- Pd-catalyzed heterocyclizations
- Oxidation reactions and Oxidative Mannich reactions
- Cross-coupling reactions
Organotrifluoroborates as versatile and stable boronic acid surrogates.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Certificates of Analysis (COA)
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Articles
These bench stable Potassium Organotrifluoroborates are useful for Suzuki-Miyaura cross-coupling reactions and have also been used for a variety of other C-C bond forming reactions. Importantly, these reagents are compatible with a wide range of functional groups and are stable to many commonly used and harsh reaction conditions.
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