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401080

Sigma-Aldrich

Bismuth(III) selenide

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Synonym(s):

Bismuth selenide

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About This Item

Empirical Formula (Hill Notation):
Bi2Se3
CAS Number:
12068-69-8
Molecular Weight:
654.84
EC Number:
235-104-7
MDL number:
MFCD00014200
UNSPSC Code:
12352300
PubChem Substance ID:
24864986
NACRES:
NA.23

form

solid

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Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

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density

6.82 g/mL at 25 °C (lit.)

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, Enabling

SMILES string

[Se]=[Bi][Se][Bi]=[Se]

InChI

1S/2Bi.3Se

InChI key

OMEPJWROJCQMMU-UHFFFAOYSA-N

General description

Bismuth(III) selenide (Bi2Se3) is a semiconducting thermoelectric material with a narrow band gap. It forms thin films by different techniques, which include solution growth, electrodeposition and molecular jet method. It acts as a topological insulator based saturable absorber.
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Application

Bi2Se3 is a metal selenide, which can be used for a variety of applications such as solar cells, light emitting diodes (LEDs), and superionic conductor. Its optical properties include a high absorption coefficient larger than 104 cm-1 and a band gap of 0.35 eV.

Signal Word

Danger

Hazard Statements

H301 + H331,H373,H410

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chemical deposition and characterization of glassy bismuth (III) selenide thin films
Pejova B and Grozdanov I
Thin Solid Films, 408(1-2), 6-10 (2002)
Q-switched ytterbium-doped fiber laser with topological insulator-based saturable absorber
Al-Masoodi AHH, et al.
Optical Engineering, 56(5), 056103-056103 (2017)

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