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325252

Sigma-Aldrich

Titanium diisopropoxide bis(acetylacetonate)

75 wt. % in isopropanol

Synonym(s):

Diisopropoxytitanium bis(acetylacetonate) solution, TYZOR® AA organic titanate, Ti(acac)2OiPr2

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About This Item

Linear Formula:
[(CH3)2CHO]2Ti(C5H7O2)2
CAS Number:
Molecular Weight:
364.26
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

form

solution

Quality Level

composition

Ti, 9-10.5% gravimetric

reaction suitability

core: titanium
reagent type: catalyst

concentration

75 wt. % in isopropanol

refractive index

n20/D 1.4935

density

0.995 g/mL at 25 °C

SMILES string

CC(C)O[Ti](OC(C)C)(O\C(C)=C\C(C)=O)O\C(C)=C\C(C)=O

InChI

1S/2C5H8O2.2C3H7O.Ti/c2*1-4(6)3-5(2)7;2*1-3(2)4;/h2*3,6H,1-2H3;2*3H,1-2H3;/q;;2*-1;+4/p-2/b2*4-3+;;;

InChI key

OVSGBKZKXUMMHS-VVDZMTNVSA-L

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Application

Titanium diisopropoxide bis (acetylacetonate) (TAA) may be used as a precursor to develop self assembled macroporous titania particles by evaporation. Commercial titanium(IV) bis(acetylacetonate) diisopropoxide was used to synthesize titanium acetylacetonate xerogels by drying, which could be further used to prepare titania films. TAA may be used as a hole blocking layer to fabricate solar cells.

Legal Information

TYZOR is a registered trademark of E. I. du Pont de Nemours and Company

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

53.6 °F - closed cup

Flash Point(C)

12 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Journal of Thermal Analysis and Calorimetry, 97(1), 39-45 (2009)
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