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Key Documents

208973

Sigma-Aldrich

Hydrogen hexachloroiridate(IV) hydrate

Synonym(s):

Dihydrogen hexachloroiridate(IV) hydrate, Hexachloroiridium(IV) acid hydrate, Hydrogen iridium hexachloride

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About This Item

Linear Formula:
H2Cl6Ir · xH2O
CAS Number:
Molecular Weight:
406.95 (anhydrous basis)
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:

form

(Powder or Crystals or Granules or Beads)

Quality Level

concentration

36.0-44.0% Ir (gravimetric)

mp

65 °C (lit.)

density

1.02 g/mL at 25 °C (lit.)

SMILES string

Cl[H].Cl[H].[H]O[H].Cl[Ir](Cl)(Cl)Cl

InChI

1S/6ClH.Ir.H2O/h6*1H;;1H2/q;;;;;;+4;/p-4

InChI key

YDVQBPXDKJKDME-UHFFFAOYSA-J

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Application

Hydrogen hexachloroiridate(IV) hydrate can be used:
  • As a precursor to prepare promoted hydrogenation catalyst for Fischer–Tropsch synthesis (FTS).
  • To fabricate dimensionally stable electrodes for oxygen evolution reactions.

Features and Benefits

Catalyzes the electrochemical synthesis of polyaniline on the surface of non-noble metal electrodes. Utilized in the formation of iridium-substituted Dawson- and Keggin-type polyoxometallates by refilling the vacant site of the lacunary precursors.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1C

Storage Class Code

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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