183695
2′-Bromoacetophenone
99%
Synonym(s):
1-Acetyl-2-bromobenzene
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About This Item
Assay
99%
form
liquid
refractive index
n20/D 1.568 (lit.)
density
1.476 g/mL at 25 °C (lit.)
functional group
bromo
SMILES string
CC(=O)c1ccccc1Br
InChI
1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
InChI key
PIMNFNXBTGPCIL-UHFFFAOYSA-N
General description
2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.
Application
2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
230.0 °F - closed cup
Flash Point(C)
110 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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