Blocking bimolecular activation pathways leads to different regioselectivity in metal-organic framework catalysis.

Blocking bimolecular activation pathways leads to different regioselectivity in metal-organic framework catalysis.

Chemical communications (Cambridge, England) (2012-07-28)

Teng Zhang, Feijie Song, Wenbin Lin

ABSTRACT

Chiral metal-organic frameworks built from a Co-salen derived dicarboxylate bridging ligand exhibited different regioselectivities from the corresponding homogeneous catalyst by shutting down bimolecular activation pathways.

MATERIALS

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236071

Sigma-Aldrich

N,N′-Bis(salicylidene)ethylenediamine, 98%

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