320390

Methanol

≥99.8%, ACS reagent

• Synonym(s): Methyl alcohol
• Linear Formula: CH₃OH
• CAS Number: 67-56-1
• Molecular Weight: 32.04
• Beilstein: 1098229
• EC Number: 200-659-6
• MDL number: MFCD00004595
• UNSPSC Code: 41116121
• PubChem Substance ID: 329753975
• NACRES: NA.21

Properties

• product name: Methanol, ACS reagent, ≥99.8%
• grade: ACS reagent
• Quality Level: 200
• vapor density: 1.11 (vs air)
• vapor pressure: 410 mmHg ( 50 °C); 97.68 mmHg ( 20 °C)
• Assay: ≥99.8%
• form: liquid
• autoignition temp.: 725 °F
• expl. lim.: 36 %
• impurities: H₂SO₄, passes test (darkened); MnO₄^- reducers, passes test; ≤0.0002 meq/g Titr. base; ≤0.0003 meq/g Titr. acid; ≤0.001% acetaldehyde; ≤0.001% acetone; ≤0.001% formaldehyde; ≤0.1% water
• evapn. residue: ≤0.001%
• color: APHA: ≤10; clear
• refractive index: n20/D 1.329 (lit.)
• bp: 64.7 °C (lit.)
• mp: −98 °C (lit.)
• density: 0.791 g/mL at 25 °C (lit.)
• format: neat
• SMILES string: CO
• InChI: 1S/CH4O/c1-2/h2H,1H3
• InChI key: OKKJLVBELUTLKV-UHFFFAOYSA-N

Description

General description

Methanol is a polar solvent and feedstock to produce chemicals and fuel additives. It can be produced through the catalytic hydrogenation of CO₂.

Application

Methanol can be used as a solvent in the:

• Palladium(II)-exchanged hydroxyapatite-catalyzed Suzuki–Miyaura cross-coupling reactions.
• Reductive amination of ketones with ammonia and dihydrogen to synthesize primary amines.

Safety Information

• Pictograms: GHS02,GHS06,GHS08
• Signal Word: Danger
• Hazard Statements: H225 - H301 + H311 + H331 - H370
• Precautionary Statements: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point(F): 49.5 °F - closed cup
• Flash Point(C): 9.7 °C - closed cup