748773
Ethyl 1H-imidazole-1-carboxylate
Synonym(s):
Heller-Sarpong Reagent, N-Carboethoxyimidazole, EtImC, Ethyl imidazolecarbamate, Sarpong reagent
About This Item
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form
liquid
refractive index
n20/D 1.472
density
1.162 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CCOC(=O)n1ccnc1
InChI
1S/C6H8N2O2/c1-2-10-6(9)8-4-3-7-5-8/h3-5H,2H2,1H3
InChI key
YICRPEGTQDSFEX-UHFFFAOYSA-N
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Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
219.9 °F
Flash Point(C)
104.4 °C
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Professor Heller and coworkers are engaged in the development of mild and chemoselective acylation reactions using carbonylazole-derived reagents. To that end, they have developed a suite of carbonylimidazole derivatives for facile and chemoselective esterification (MImC, etc.) and amidation (WImC) of carboxylic acids, in collaboration with Professor Richmond Sarpong.
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