A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

Journal of the American Chemical Society (2009-08-25)

Shunsuke Chiba, Yan-Jun Xu, Yi-Feng Wang

PMID19697931

ZUSAMMENFASSUNG

A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azaheterocycles.

MATERIALIEN

Produktnummer

Marke

Produktbeschreibung

697230

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocen]dichlorpalladium(II)