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CRM68471

Supelco

Flucythrinate

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Sinónimos:

α-Cyano-3-phenoxybenzyl 4-difluoromethoxy-α-isopropylphenylacetate

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About This Item

Fórmula empírica (notación de Hill):
C26H23F2NO4
Número de CAS:
70124-77-5
Peso molecular:
451.46
MDL number:
MFCD00137383
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

300

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

2-8°C

SMILES string

CC(C)C(C(=O)OC(C#N)c1cccc(Oc2ccccc2)c1)c3ccc(OC(F)F)cc3

InChI

1S/C26H23F2NO4/c1-17(2)24(18-11-13-21(14-12-18)32-26(27)28)25(30)33-23(16-29)19-7-6-10-22(15-19)31-20-8-4-3-5-9-20/h3-15,17,23-24,26H,1-2H3

InChI key

GBIHOLCMZGAKNG-UHFFFAOYSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Flucythrinate is a synthetic a-cyano pyrethroid insecticide that acts as a voltage gated sodium channel agonist. It finds its use to provide protection against a variety of sucking insects, beetles, and lepidoptera in cotton and pome fruits.
Flucythrinate is not approved for its use in the European Union (EU) as per the Commission Regulation (EC) No 2076/2002 of 20th November 2002 as a plant protection agent under the Regulation (EC) No. 1107/2009, repealing the directive 91/414/EEC. Flucythrinate is measured and reported along with other mixtures of its constituent isomers (sum of isomers). But a default maximum residue limit (MRL) of 0.01 mg/kg and 0.02 mg/kg is applicable for its presence in fresh/frozen fruits and tree nuts respectively according to Reg. (EU) 2015/868.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The methiocarb CRM may also find use as given below:
  • Development of a class selective enzyme-linked immunosorbent assay (ELISA) to screen a-cyano pyrethroids and their metabolites
  • Comparison between two sample preparation techniques-dispersive liquid-liquid microextraction (DLLME) and QuEChERS-DLLME, followed by gas chromatography-electron capture detection (GC-ECD) for the determination of 10 pyrethroids from different fruit juice samples
  • Multi-residue analysis of 133 pesticide residues in chenpi samples using a modified QuEChERS method and gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Simultaneous determination of 78 pesticides in black tea samples using multi-walled carbon nanotubes (MWCNTs) for dispersive solid phase extraction (d-SPE) accompanied by quantification with gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Development of a method based on gas chromatography-mass spectrometry (GC-MS) in negative chemical ionization mode to determine 17 pyrethroid residues in garlic, onion, spring onion, and chili samples
  • Development and validation of a method for multi-residue analysis of 124 pesticides in rice samples using modified QuEChERS extraction and gas chromatography-tandem mass spectrometry (GC-MS/MS)

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

113.0 °F

flash_point_c

45 °C

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Certificados de análisis (COA)

Lot/Batch Number
BCCG0597

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Julia Ortmann et al.
ALTEX, 39(1), 82-94 (2021-08-08)
The photomotor response (PMR) of zebrafish embryos, a light pulse-triggered undirected movement, is known to be altered by neuroactive chemicals. Here, we developed an approach for data analysis of the distribution of PMR movement activities along the time axis; differences
Xue Hou et al.
Food chemistry, 153, 121-129 (2014-02-05)
A modified QuEChERS (quick, easy, cheap, effective, rugged and safe) method using multi-walled carbon nanotubes (MWCNTs) as a dispersive solid phase extraction (d-SPE) absorbent was established for analysis of 78 pesticide residues in tea. A 6 mg MWCNT sample was
Yaohai Zhang et al.
Food chemistry, 159, 367-373 (2014-04-29)
Dispersive liquid-liquid microextraction (DLLME) sample preparation and the quick, easy, cheap, effective, rugged and safe (QuEChERS) method combined with DLLME were developed and compared for the analysis of ten pyrethroids in various fruit juices using gas chromatography-electron capture detection (GC-ECD).
Xue Hou et al.
Food chemistry, 138(2-3), 1198-1205 (2013-02-16)
A modified QuEChERS method for simultaneous determination of 124 pesticide residues in rice was established and validated. The rice samples were initially extracted with acetonitrile (MeCN), and the targeted pesticides were purified following the dispersive solid phase extraction (d-SPE) cleanup

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