31690

Dietiléter

≥99.8% (GC), puriss. p.a., ACS reagent, contains ~0.0005% 2, 6-di-tert-butyl-4-methylphenol as stabilizer

• Sinónimos: Éter, Éter etílico
• Fórmula lineal: (CH₃CH₂)₂O
• Número de CAS: 60-29-7
• Peso molecular: 74.12
• Beilstein/REAXYS Number: 1696894
• EC Number: 200-467-2
• MDL number: MFCD00011646
• UNSPSC Code: 12352112
• PubChem Substance ID: 57648602
• assay: ≥99.8% (GC)
• technique(s): GC/GC: suitable
• bp: 34.6 °C (lit.)

Propiedades

• Nombre del producto: Dietiléter, puriss. p.a., ACS reagent, ≥99.8% (GC)
• grade: ACS reagent; puriss. p.a.
• vapor density: 2.6 (vs air)
• assay: ≥99.8% (GC)
• form: liquid
• autoignition temp.: 320 °F
• contains: ~0.0005% 2,6-di-tert-butyl-4-methylphenol as stabilizer
• expl. lim.: 36.5 %
• technique(s): GC/GC: suitable
• impurities: ≤0.00003% peroxides (as H₂O₂); ≤0.0002 meq/g Titr. acid; ≤0.0005% free acid (as CH₃COOH); ≤0.001% acetaldehyde (CH₃CHO); ≤0.001% formaldehyde (HCHO); ≤0.1% water; <0.002% ketone (as CH₃COCH₃)
• evapn. residue: ≤0.001%
• refractive index: n20/D 1.3530 (lit.); n20/D 1.353
• bp: 34.6 °C (lit.)
• mp: −116 °C (lit.)
• density: 0.706 g/mL at 25 °C (lit.)
• cation traces: Al: ≤0.5 mg/kg; Ba: ≤0.1 mg/kg; Bi: ≤0.1 mg/kg; Ca: ≤0.5 mg/kg; Cd: ≤0.05 mg/kg; Co: ≤0.02 mg/kg; Cr: ≤0.02 mg/kg; Cu: ≤0.02 mg/kg; Fe: ≤0.1 mg/kg; K: ≤0.5 mg/kg; Li: ≤0.1 mg/kg; Mg: ≤0.1 mg/kg; Mn: ≤0.02 mg/kg; Mo: ≤0.1 mg/kg; Na: ≤0.5 mg/kg; Ni: ≤0.02 mg/kg; Pb: ≤0.1 mg/kg; Sr: ≤0.1 mg/kg; Zn: ≤0.1 mg/kg
• SMILES string: CCOCC
• InChI: 1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3
• InChI key: RTZKZFJDLAIYFH-UHFFFAOYSA-N

Descripción

General description

Diethyl ether (DEE) is widely employed as solvent for Grignard synthesis. Its efficacy as solvent for Formalin-ether (F-E) sedimentation technique has been studied. It has been reported as a hydroboration solvent. DEE is a promising compression-ignition fuel and its energy density is much higher than ethanol. It is also one of the components in a blend used in diesel fuel.

Application

Diethyl ether may be employed as solvent for the oxidation of secondary alcohols into ketones. It may be employed as solvent in the preparation of triblock copolymer of PCL-PEG-PCL, acrylated PCL-PEG-PCL and the pentablock copolymer PAE-PCL-PEG-PCL-PAE [PAE = poly(β-amino ester), PEG = poly(ethylene glycol), PCL = poly(ε-caprolactone)].

Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

Sales restrictions may apply

Información de seguridad

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H224,H302,H336
• pcodes: P210 - P233 - P240 - P241 - P301 + P312 - P403 + P233
• Hazard Classifications: Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH019,EUH066
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: -40.0 °F - closed cup
• flash_point_c: -40 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves