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21580

Sigma-Aldrich

Hexanoic anhydride

purum, ≥97.0% (GC)

Sinónimos:

Caproic anhydride

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About This Item

Fórmula lineal:
[CH3(CH2)4CO]2O
Número de CAS:
2051-49-2
Peso molecular:
214.30
Beilstein/REAXYS Number:
1776561
EC Number:
218-121-4
MDL number:
MFCD00009509
UNSPSC Code:
12352100
PubChem Substance ID:
329752175
NACRES:
NA.22

grade

purum

Quality Level

200

assay

≥97.0% (GC)

form

liquid

refractive index

n20/D 1.428 (lit.)
n20/D 1.429

bp

246-248 °C (lit.)

solubility

ethanol: soluble 1 g/10 mL, clear, colorless

density

0.928 g/mL at 20 °C (lit.)

SMILES string

CCCCCC(=O)OC(=O)CCCCC

InChI

1S/C12H22O3/c1-3-5-7-9-11(13)15-12(14)10-8-6-4-2/h3-10H2,1-2H3

InChI key

PKHMTIRCAFTBDS-UHFFFAOYSA-N

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Categorías relacionadas

Application

Hexanoic anhydride has been used in:
  • green synthesis of esters of acyclovir (acyclovir prodrugs)
  • preparation of hexanoyl-modified chitosan nanoparticles and chitosan-based polymeric surfactants via N-acylation of chitosans

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
BCCB7907
BCCB2606
BCBW3585
BCBW3584
BCBV2183

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Kashappa Goud Desai et al.
Drug delivery, 13(5), 375-381 (2006-08-01)
Hexanoyl chitosan was synthesized through a coupling reaction between chitosan and hexanoic anhydride. Proton nuclear magnetic resonance (1HNMR) and fourier-transform infrared (FTIR) spectroscopy studies showed the formation of hexanoyl chitosan. The nanoparticles of hexanoyl chitosan were prepared through ionotropic gelation
Rubén de Regil-Hernández et al.
Chemical & pharmaceutical bulletin, 59(9), 1089-1093 (2011-09-02)
Different green synthesis of alkyl esters of acyclovir (acyclovir prodrugs) is described. Hexanoic, decanoic, dodecanoic and tetradecanoic acyclovir esters were synthesized reacting acyclovir and the respective acid anhydride in dimethyl sulfoxide (DMSO), in solvents from renewable sources and without solvent
Moo-Yeal Lee et al.
International journal of biological macromolecules, 36(3), 152-158 (2005-07-14)
Chitosan-based polymeric surfactants (CBPSs) were prepared by N-acylation of chitosans (chitosan 10 and 500) with several acid anhydrides such as hexanoic (C6), lauric (C12), and palmitic (C16) anhydrides. Among the CBPS samples, CBPSs having a good solubility at pH 4.0
Marco Igor Valencia-Sánchez et al.
Molecular cell, 74(5), 1010-1019 (2019-04-15)
The essential histone H3 lysine 79 methyltransferase Dot1L regulates transcription and genomic stability and is deregulated in leukemia. The activity of Dot1L is stimulated by mono-ubiquitination of histone H2B on lysine 120 (H2BK120Ub); however, the detailed mechanism is not understood.

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