Todas las fotos(1)

Documentos

8.12382

Titanium(IV) chloride

Name: Titanium(IV) chloride
Brand: MM

for synthesis

Sinónimos:

Titanium(IV) chloride, Titanium tetrachloride

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización

Todas las fotos(1)

About This Item

Fórmula empírica (notación de Hill):

Cl₄Ti

Número de CAS:

7550-45-0

Peso molecular:

189.68

MDL number:

MFCD00011267

UNSPSC Code:

12352302

EC Index Number:

231-441-9

vapor pressure

12 hPa ( 20 °C)

Quality Level

200

form

liquid

potency

3160 mg/kg LD₅₀, skin (Rabbit)

bp

136 °C/1013 hPa

mp

-24 °C

density

1.728 g/cm³ at 20 °C

storage temp.

2-30°C

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

Application

Titanium(IV) chloride can be used as a Lewis acid catalyst:

In the ortho acylation of aryl alcohols to synthesize corresponding ortho C-acylated products.
To synthesize various chlorinated compounds via Baylis−Hillman reaction reactions of aryl aldehydes with methyl vinyl ketone in the presence of Lewis base.
To prepare 3,4-dihydropyrimidin-2(1H)-ones and thiones by Biginelli condensation reaction of aldehyde, 1,3-dicarbonyl compound, and urea or thiourea.
In the hydrodefluorination reaction in the presence of triethylsilane as the reducing agent.

Analysis Note

Assay (argentometric): ≥ 97.0 %
Identity (ICP-OES): passes test

pictograms

GHS05,GHS06

signalword

Danger

hcodes

H314 - H330 - H335

pcodes

P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH014

Storage Class

6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Titanium(IV) chloride and the amine-promoted baylis-hillman reaction

M Shi, et al.

Organic Letters, 2(16), 2397-2400 (2000)

Titanium (IV) chloride catalyzed one-pot synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones and thiones

Nagawade RR, et al.

Mendeleev Communications, 15(4), 150-151 (2005)

Titanium (IV) chloride-mediated ortho-acylation of phenols and naphthols

Bensari A and Zaveri NT

Synthesis, 2003(02), 0267-0271 (2003)

Transformation of Trifluorotoluenes Triggered by Titanium (IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes

Yamada T, et al.

advanced synthesis and catalysis, 358(1), 62-66 (2016)