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P22389

Sigma-Aldrich

Phenyl dichlorophosphate

≥95%

Sinónimos:

Phenyl phosphodichloridate, Phenyl phosphorodichloridate, Phenyl phosphoryl dichloride

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About This Item

Fórmula lineal:
C6H5OP(O)Cl2
Número de CAS:
770-12-7
Peso molecular:
210.98
Beilstein/REAXYS Number:
511863
EC Number:
212-220-6
MDL number:
MFCD00002067
UNSPSC Code:
12352100
PubChem Substance ID:
24898297
NACRES:
NA.22

Quality Level

200

assay

≥95%

refractive index

n20/D 1.523 (lit.)

bp

241-243 °C (lit.)

density

1.412 g/mL at 25 °C (lit.)

SMILES string

ClP(Cl)(=O)Oc1ccccc1

InChI

1S/C6H5Cl2O2P/c7-11(8,9)10-6-4-2-1-3-5-6/h1-5H

InChI key

TXFOLHZMICYNRM-UHFFFAOYSA-N

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Application

Reagent for the preparation of phosphate diesters.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
STBJ7558
STBF6200V
STBC6044V
STBC6847V
STBC6484V

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Diphenyl phosphoryl chloride 96%

Sigma-Aldrich

344249

Diphenyl phosphoryl chloride

Phenylphosphonothioic dichloride AldrichCPR

Sigma-Aldrich

CDS000508

Phenylphosphonothioic dichloride

The Journal of Organic Chemistry, 53, 2077-2077 (1988)
Chun-Wei Kuo et al.
Molecules (Basel, Switzerland), 17(11), 13662-13672 (2012-11-22)
Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
Yvan Ecochard et al.
Molecules (Basel, Switzerland), 24(9) (2019-05-15)
Epoxy materials have attracted attention for many applications that require fireproof performance; however, the utilization of hazardous reagents brings about potential damage to human health. Eugenol and cardanol are renewable, harmless resources (according to ECHA) that allow the achievement of
Xiaoming Zhou et al.
Chemosphere, 235, 163-168 (2019-07-01)
Two novel phosphorus-containing copolyesters were synthesized by direct polycondensation reaction of phenyl dichlorophosphate, 1,4-succinic acid and 1,4-butanediol using stannous chloride (SnCl2) and 4-Methylbenzenesulfonic acid as catalyst, and its chemical structures were identified by 1H and 31P nuclear magnetic resonances (1H
R M Dawson et al.
Analytical biochemistry, 170(2), 451-455 (1988-05-01)
An improved method for assaying carbamylated acetylcholinesterase is described which has substantial benefits over current methods. Acetylcholinesterase was carbamylated with neostigmine and diluted extensively into buffer to allow decarbamylation to occur. At various times, phenyldichlorophosphate was added to the mixture
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