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Merck

GF55991076

Samarium

rod, 50mm, diameter 6.35mm, cast, 99%

Sinónimos:

Samarium, SM007910

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About This Item

Fórmula empírica (notación de Hill):
Sm
Número de CAS:
Peso molecular:
150.36
MDL number:
UNSPSC Code:
12141612
PubChem Substance ID:
NACRES:
NA.23

assay

99%

form

rod

manufacturer/tradename

Goodfellow 559-910-76

resistivity

91.4 μΩ-cm, 0°C

L × diam.

50 mm × 6.35 mm

bp

1794 °C (lit.)

mp

1074 °C (lit.)

density

7.47 g/mL at 25 °C (lit.)

SMILES string

[Sm]

InChI

1S/Sm

InChI key

KZUNJOHGWZRPMI-UHFFFAOYSA-N

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General description

For updated SDS information please visit www.goodfellow.com.

Legal Information

Product of Goodfellow

pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Water-react 3

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificados de análisis (COA)

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A N Serafini
Cancer, 88(12 Suppl), 2934-2939 (2000-07-18)
In patients with bone pain due to metastatic disease, intravenous systemic radioisotope therapy may be a useful adjunct to other methods for palliating pain. Various studies have been performed utilizing a short-lived radioisotope conjugated to a tetraphosphonate (samarium 153 lexidronam)
Christine Beemelmanns et al.
Chemical Society reviews, 40(5), 2199-2210 (2011-01-19)
In this tutorial review we discuss recent advances in the field of ketyl-(het)arene cyclisations promoted by samarium diiodide and related processes. Couplings of samarium ketyls with carbon-carbon multiple bonds are perhaps the most useful reactions to create carbocycles and heterocycles
K C Nicolaou et al.
Angewandte Chemie (International ed. in English), 48(39), 7140-7165 (2009-08-29)
Introduced by Henri Kagan more than three decades ago, samarium diiodide (SmI(2)) has found increasing application in chemical synthesis. This single-electron reducing agent has been particularly useful in C-C bond formations, including those found in total synthesis endeavors. This Review
José M Concellón et al.
Chemical Society reviews, 39(11), 4103-4113 (2010-08-05)
Samarium metal and samarium diiodide have become important tools as selective cyclopropanating agents in organic synthesis due to their high chemo- and stereoselectivity. Therefore, Sm and SmI(2) are the ideal reagents to prepare cyclopropane derivatives. This tutorial review highlights C-C
Hiroshi Suizu et al.
Organic letters, 17(1), 126-129 (2014-12-17)
A new synthetic route to clavilactone B, a naturally occurring inhibitor of epidermal growth factor receptor (EGFR) tyrosine kinase, is disclosed. The route features a sequential samarium-mediated radical cyclization-fragmentation of an indanone derivative, which provides rapid access to a 10-membered

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