939633

Indoline-2-thione

≥-95%

• Sinónimos: 2,3-Dihydro-1H-indole-2-thione
• Fórmula empírica (notación de Hill): C₈H₇NS
• Número de CAS: 496-30-0
• Peso molecular: 149.21
• MDL number: MFCD09971323
• UNSPSC Code: 12352100

Propiedades

• Quality Level: 100
• assay: ≥-95%
• form: powder or crystals
• reaction suitability: reaction type: Photocatalysis
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• color: white to yellow
• greener alternative category: Aligned
• SMILES string: S=C1NC2=CC=CC=C2C1
• InChI: InChI=1S/C8H7NS/c10-8-5-6-3-1-2-4-7(6)9-8/h1-4H,5H2,(H,9,10)
• InChI key: IGJWTYFTQNHSEK-UHFFFAOYSA-N

Descripción

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Indoline-2-thione is a indole thiolate has been used in:

• The MgI₂-catalyzed nucleophilic ring opening of donor-acceptor cyclopropanes
• The synthesis of indole-fused dihydrothiopyrano scaffolds via [3+3] annulations of donor-acceptor cyclopropanes
• The preparation of 2-carboxylated thieno [2,3- b] indoles

Also used as a catalytic photoreductant in:

• The synthesis of thioethers from aryl chlorides & alcohols

Features and Benefits

1-Methylindoline-2-thione is an affordable indole thiolate that is useful in general synthesis as well as the transition-metal free photocatalytic reduction of a range of strong polar C-F, C-O and C-Cl bonds.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3