89025

Copper(I) thiophenolate

≥98.0% (RT)

• Sinónimos: PhSCu, Copper(I) thiophenoxide, Phenylthiocopper(I), Thiophenol copper(I) salt
• Fórmula lineal: C₆H₅SCu
• Número de CAS: 1192-40-1
• Peso molecular: 172.71
• Beilstein/REAXYS Number: 3709171
• MDL number: MFCD00064893
• UNSPSC Code: 12352300
• PubChem Substance ID: 24889167
• NACRES: NA.22

Propiedades

• assay: ≥98.0% (RT)
• form: solid
• reaction suitability: core: copper; reagent type: catalyst
• mp: 280 °C (dec.) (lit.)
• SMILES string: [Cu]Sc1ccccc1
• InChI: 1S/C6H6S.Cu/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
• InChI key: PNNJYDODNCALKD-UHFFFAOYSA-M

Descripción

Application

Reagents used as the source of nucleophilic phenyl sulfide for preparation of lithiumalkyl(phenylthio)cuprates and organophosphinecopper(I) phenylthiolatecomplexes

Other Notes

Reagent for the simple preparation of lithium (phenylthio)alkyl-cuprates from lithium alkyls, used for conjugate addition to α,β-enones

Información de seguridad

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges