774677

Cyclohexylmagnesium chloride solution

1.0 M in 2-methyltetrahydrofuran

• Sinónimos: Chlorocyclohexylmagnesium
• Fórmula empírica (notación de Hill): C₆H₁₁ClMg
• Número de CAS: 931-51-1
• Peso molecular: 142.91
• Beilstein/REAXYS Number: 3535440
• MDL number: MFCD00003816
• UNSPSC Code: 12352103
• PubChem Substance ID: 329767705
• NACRES: NA.22

Propiedades

• form: solution
• reaction suitability: reaction type: Grignard Reaction
• greener alternative product characteristics: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• concentration: 1.0 M in 2-methyltetrahydrofuran
• density: 0.915 g/mL at 25 °C
• greener alternative category: , Aligned
• storage temp.: 2-8°C
• SMILES string: Cl[Mg]C1CCCCC1
• InChI: 1S/C6H11.ClH.Mg/c1-2-4-6-5-3-1;;/h1H,2-6H2;1H;/q;;+1/p-1
• InChI key: WMJMABVHDMRMJA-UHFFFAOYSA-M

Descripción

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Nucleophilic reagent is commonly used in substitution and addition reactions.

Packaging

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Other Notes

Development of GSK′s reagent guides – embedding sustainability into reagent selection.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Información de seguridad

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H302,H314
• pcodes: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• supp_hazards: EUH014,EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 14.0 °F
• flash_point_c: -10 °C