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Merck

711721

Sigma-Aldrich

1-Ethyl-3-methylimidazolium tetrafluoroborate

≥98% (HPLC)

Sinónimos:

EMIMBF4

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About This Item

Fórmula empírica (notación de Hill):
C6H11BF4N2
Número de CAS:
Peso molecular:
197.97
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

≥98% (HPLC)

form

liquid

impurities

≤0.5% water

refractive index

n20/D 1.413 (lit.)

bp

>350 °C (lit.)

mp

15 °C (lit.)

density

1.294 g/mL at 25 °C (lit.)

SMILES string

F[B-](F)(F)F.CCn1cc[n+](C)c1

InChI

1S/C6H11N2.BF4/c1-3-8-5-4-7(2)6-8;2-1(3,4)5/h4-6H,3H2,1-2H3;/q+1;-1

InChI key

CUNYTRQQXKCRTJ-UHFFFAOYSA-N

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General description

1-Ethyl-3-methylimidazolium tetrafluoroborate is an air and water stable, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-ethyl-3-methylimidazolium bromide with tetrafluoroboric acid.

Application


  • 1-Ethyl-3-methylimidazolium tetrafluoroborate-doped high ionic conductivity gel electrolytes with reduced anodic reaction potentials for electrochromic devices: This study reports the preparation of a 1-Ethyl-3-methylimidazolium tetrafluoroborate ([Emim] BF4)-doped Poly(methyl methacrylate)(PMMA)-based gel electrolyte for electrochromic applications, showing improved ionic conductivity and reduced anodic reaction potentials (Tang et al., 2017).

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Rapid Preparation of Room Temperature Ionic Liquids with Low Water Content as Characterized with a ta-C: N Electrode.
Jarosova R and Swain GM.
Journal of the Electrochemical Society, 162(8), H507-H511 (2015)
Viscosity Measurements for Binary Mixtures of 1-Ethyl-3-Methylimidazolium Tetrafluoroborate with Acetonitrile, Ethylene Glycol, and Methanol
Fan, Xian-Heng, Yan-Ping Chen, and Chie-Shaan Su.
Journal of Solution Chemistry, 45.10, 1377-1390 (2016)
NMR evidence of hydrogen bonding in 1-ethyl-3-methylimidazolium-tetrafluoroborate room temperature ionic liquid
Huang, Jing-Fang, et al.
Inorgorganica Chimica Acta, 320.1, 7-11 (2001)
Densities and viscosities of binary liquid mixtures of 1-ethyl-3-methylimidazolium tetrafluoroborate with acetone, methyl ethyl ketone, and N-methyl-2-pyrrolidone
Fan, Xian-Heng, Yan-Ping Chen, and Chie-Shaan Su.
Journal of the Taiwan Institute of Chemical Engineers, 61, 117-123 (2016)
The phase behaviour of 1-alkyl-3-methylimidazolium tetrafluoroborates; ionic liquids and ionic liquid crystals.
Holbrey JD and Seddon KR.
J. Chem. Soc., Dalton Trans., 13, 2133-2140 (1999)

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