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Merck

699608

Sigma-Aldrich

Phosphoric acid solution

NMR reference standard, 85% in D2O (99.9 atom % D), NMR tube size 3 mm × 8 in.

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About This Item

Fórmula lineal:
H3PO4
Número de CAS:
Peso molecular:
98.00
Beilstein/REAXYS Number:
1921286
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.12

grade

NMR reference standard

Quality Level

assay

83.5-86.5% (gravimetric)

form

solution

concentration

85% in D2O (99.9 atom % D)

technique(s)

NMR: suitable

NMR tube size

3 mm × 8 in.

density

1.481 g/cm3

SMILES string

OP(O)(O)=O

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

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Features and Benefits

31P sensitivity

Quantity

3 mm O.D. tube contains 0.235 mL.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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A highly enantioselective hydroamination/N-sulfonyliminium cyclization cascade is reported using a combination of gold(I) and chiral phosphoric acid catalysts. An initial 5-exo-dig hydroamination and a subsequent phosphoric acid catalyzed cyclization process provide access to complex sulfonamide scaffolds in excellent yield and
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Journal of the American Chemical Society, 136(43), 15366-15378 (2014-10-18)
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