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Merck

685445

Sigma-Aldrich

Halloysite Nanoclay

Sinónimos:

Kaolin clay

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About This Item

Fórmula lineal:
Al2Si2O5(OH)4 · 2 H2O
Número de CAS:
Peso molecular:
294.19
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

nanopowder

diam. × L

30-70 nm × 1-3 μm , nanotube

surface area

64 m2/g

color

75-96, Hunter Brightness

refractive index

n20/D 1.54

pore size

1.26-1.34 mL/g pore volume

capacity

8.0 meq/g cation exchange capacity

density

2.53 (true specific gravity)

SMILES string

O.O.O[Si](O)(O[Al]=O)O[Si](O)(O)O[Al]=O

InChI

1S/2Al.H4O7Si2.2H2O.2O/c;;1-8(2,3)7-9(4,5)6;;;;/h;;1-2,4-5H;2*1H2;;/q2*+1;-2;;;;

InChI key

HEFIDAICLOZRRO-UHFFFAOYSA-N

General description

Halloysite nanoclay has a tube like morphology. It shows low electrical, thermal conductivity and strong hydrogen interactions, on account of which the inner hydroxyl groups show greater stability than the surface hydroxyl groups in halloysite. The loss of hole water occurs at nearly 300 °C.
Similar to montmorillonite, halloysite consists of two layers of aluminosilicate in 1:1 Al:Si ratio. Significant improvements in thermal, mechanical properties have been reported on addition of halloysite nanotubes in polymer composites.

Application

Halloysite is frequently used as a reinforcement in various nanocomposites, some of which are listed here:
Isotactic propylene-halloysite nanocomposites.
Alloy composites by electroless/ autocatalytic deposition.
Poly(butylene terephthalate) (PBT) composites.
Zinc–halloysite nanotube (HNT) composite coatings.
Halloysite nanotube–hydroxyapatite–hyaluronic acid films.
Halloysite combined with polyamide, polypropylene, poly(ε-caprolactone) and fluroelastomers.
Its tube like morphology, high aspect ratio, and low percolation enables interesting applications as reinforcements in nanocomposites.

Legal Information

Product of Applied Minerals, Inc. Customers may obtain additional technical support and purchase commercial quantities at appliedminerals.com

Storage Class

11 - Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Effects of filler type on the nonisothermal crystallization kinetics of poly(butylene terephthalate) (PBT) composites
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Journal of Applied Polymer Science, 123(1), 77-91 (2012)
Joussein E. et al.
Clay Minerals, 40, 383-383 (2005)
Electrophoretic deposition of composite halloysite nanotube?hydroxyapatite?hyaluronic acid films
Deen I and Zhitomirsky I
J. Alloy Compounds, 586(1), S531-S534 (2014)
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S R Levis et al.
International journal of pharmaceutics, 243(1-2), 125-134 (2002-08-15)
Halloysite supplied from New Zealand was shown by electron microscopy to be composed mainly of hollow microtubules having typical dimensions of 2-3 microm long and 0.3/0.1 microm outer/inner diameter. Aggregates of microtubules, double tubules and occasional split or partially unrolled

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