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Merck

445711

Sigma-Aldrich

Poly(3-octylthiophene-2,5-diyl)

regioregular

Sinónimos:

P3OT

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About This Item

Fórmula lineal:
(C12H18S)n
Número de CAS:
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.23

Quality Level

mol wt

average Mn ~34,000

color

black

conductivity

1 × 10-6 S/cm
~1 × 103 S/cm (when doped with iodine)

mp

190 °C
198-211 °C

fluorescence

λex 442 nm; λem 562 nm in chloroform

OPV device performance

ITO/PEDOT:PSS/P3OT:PC61BM (1:2)/LiF/Al

  • Short-circuit current density (Jsc): 5.55 mA/cm2
  • Open-circuit voltage (Voc): 0.5 V
  • Fill Factor (FF): 0.33
  • Power Conversion Efficiency (PCE): 0.91 %

semiconductor properties

P-type (mobility=1E-4-1E-1)

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General description

Greater than 98.5% head-to-tail regiospecific conformation.
Poly(3-octylthiophene-2,5-diyl) (P3OT) is an alkylthiophene based conductive polymer with high electroluminescence, which is soluble in most of the organic solvents. It can be prepared by the electrochemical polymerization of 3-octylthiophene (3OT). It is hydrophobic and can be used as a transducer for ion selective electrodes.

Application

For the characterization and solid-state properties of this polymer, see J. Am. Chem. Soc. .
P3OT forms a nanocomposite with carbon nanotubes (CNTs) for devising a high performance semiconducting material. It can also be used as a π-conjugating polymer for the fabrication of organic electronic based devices which include polymeric diodes, solar cells and photovoltaic modules.
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials. Poly (3-octylthiophene-2,5-diyl) (P3OT)-single walled carbon nanotubes composites were prepared., 3 Doped P3OT may be used in NO2 sensing applications. 2
Conducting polymer.
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
Used in organic field-effect transistors and in polymer-based solar cells.

Features and Benefits

Good processability, environmental stability and electroactivity.

Packaging

Packaged in glass bottles

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Visite la Librería de documentos

Physical characterizations of semi-conducting conjugated polymer-CNTs nanocomposites.
Abu-Abdeen M, et al.
Journal of Polymer Research, 19(3), 1-9 (2012)
Semiconducting polymer diodes: Large size, low cost photodetectors with excellent visible-ultraviolet sensitivity
Yu, G and Pakbaz, K and Heeger, AJ
Applied Physics Letters, 64(25), 3422-3424 (1994)
Physical characterizations of semi-conducting conjugated polymer-CNTs nanocomposites
Abu-Abdeen M, et al.
Journal of Polymer Research, 19(3), 9839-9839 (2012)
Structural analysis of poly (3-alkylthiophene) s
Leclerc M, et al.
Die Makromolekulare Chemie, 190(12), 3105-3116 (1989)
Single-wall carbon nanotube/conjugated polymer photovoltaic devices
Kymakis E and Amaratunga G
Applied Physics Letters, 80(1), 112-114 (2002)

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The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

Intrinsically stretchable active layers for organic field-effect transistors (OFET) are discussed. Polymer structural modification & post-polymerization modifications are 2 methods to achieve this.

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