403083

1,3-Dibromoadamantane

99%

• Fórmula empírica (notación de Hill): C₁₀H₁₄Br₂
• Número de CAS: 876-53-9
• Peso molecular: 294.03
• MDL number: MFCD00077218
• UNSPSC Code: 12352100
• PubChem Substance ID: 24865163
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: 99%
• form: powder
• mp: 108-110 °C (lit.)
• SMILES string: Br[C@]12C[C@@H]3C[C@H](C1)C[C@@](Br)(C3)C2
• InChI: 1S/C10H14Br2/c11-9-2-7-1-8(4-9)5-10(12,3-7)6-9/h7-8H,1-6H2/t7-,8+,9+,10-
• InChI key: HLWZKLMEOVIWRK-FIRGSJFUSA-N

Descripción

General description

1,3-Dibromoadamantane is reported to react with diphenylphosphide ions (Ph₂P^-) under photostimulation by the S_RN1 mechanism. The viscosity-dependent retarding effect of 1,3-dibromoadamantane in highly viscous polymeric chlorotrifluoroethene has been studied by 13C NMR relaxation measurements. Preparation of 1,3-dibromoadamantane via dibromination of adamantine has been reported.

Application

1,3-Dibromoadamantane may be used in the preparation of 1,3-bis(phenyldimethylsilyl)adamantine.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)