377023
2-Iodopropane-d7
98 atom % D, contains copper as stabilizer
Sinónimos:
Isopropyl-d7 iodide
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About This Item
Fórmula lineal:
(CD3)2CDI
Número de CAS:
Peso molecular:
177.04
MDL number:
UNSPSC Code:
12142201
PubChem Substance ID:
NACRES:
NA.21
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isotopic purity
98 atom % D
assay
99% (CP)
form
liquid
contains
copper as stabilizer
technique(s)
NMR: suitable
impurities
≤0.5% water
water
refractive index
n20/D 1.4925 (lit.)
bp
88-90 °C
density
1.774 g/mL at 25 °C (lit.)
mass shift
M+7
storage temp.
2-8°C
SMILES string
[2H]C([2H])([2H])C([2H])(I)C([2H])([2H])[2H]
InChI
1S/C3H7I/c1-3(2)4/h3H,1-2H3/i1D3,2D3,3D
InChI key
FMKOJHQHASLBPH-YYWVXINBSA-N
General description
2-Iodopropane-d7 is 2-iodopropane with all the hydrogen atoms substituted by deuterium. Its synthesis from 2-propanol-d8 has been reported.
Application
2-Iodopropane-d7 may be used in the preparation of deuterium labeled prenyldiphosphate and prenylcysteine derivatives, and 1-(isopentylsulfonyl)benzene-d7.
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
107.6 °F - closed cup
flash_point_c
42.00 °C - closed cup
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Thangaiah Subramanian et al.
Journal of labelled compounds & radiopharmaceuticals, 56(8), 370-375 (2013-11-29)
A Wittig reaction employing Li(CD3)2CP(C6H5)3 was used to prepare d6-farnesol and d6-geranylgeraniol. Reductive amination of aniline-2,3,4,5,6-d5 was used to prepare the unnatural isoprenoid analogues d5-anilinogeraniol and d5-anilinofarnesol. All of these deuterated isoprenols were elaborated into their diphosphate and cysteine thioether
Maya Kamao et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 859(2), 192-200 (2007-10-19)
Sensitive quantification method for fat-soluble vitamins in human breast milk by liquid chromatography-tandem mass spectrometry was developed. Vitamins A, D and E were extracted from 10.0 mL of breast milk after saponifying by basic condition. Vitamin K derivatives were extracted
Chemistry of the 2, 5-didehydropyridine biradical: Computational, kinetic, and trapping studies toward drug design.
Hoffner J, et al.
Journal of the American Chemical Society, 120(2), 376-385 (1998)
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