346276
Tetrakis(acetonitrile)copper(I) hexafluorophosphate
97%
Sinónimos:
Copper(I) tetrakis(acetonitrile) hexafluorophosphate, Cuprous tetrakis(acetonitrile) hexafluorophosphate
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About This Item
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Quality Level
assay
97%
form
solid
reaction suitability
core: copper
reagent type: catalyst
mp
160 °C (dec.) (lit.)
SMILES string
[Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F
InChI
1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1
InChI key
GNQXUMGHBSAQBV-UHFFFAOYSA-N
Application
Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:
It can also be used as a copper precursor:
- For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
- To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
- To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
- For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Los clientes también vieron
Differential conductance (dI/dV) imaging of a heterojunction-nanorod.
Nanotechnology, 28(9), 095705-095705 (2017)
Synthesis and characterization of [Cu (NHC)2] X complexes: Catalytic and mechanistic studies of hydrosilylation reactions.
Chemistry?A European Journal , 14(1), 158-168 (2008)
Structural Characterization and Photochemical Properties of Mono-and Bimetallic Cu-Mabiq Complexes.
Inorganic Chemistry, 28(9), 095705-095705 (2018)
Tetrakis (acetonitrile) copper (I) Hexafluorophosphate as an Efficient Catalyst for the Synthesis of Triazolo [1, 2-a] indazole-1, 3, 8-trione and 2Hindazolo [2, 1-b] phthalazine-trione Derivatives.
Letters in Organic Chemistry, 9(2), 128-132 (2012)
Two luminescent pseudo-polymorphic cuprous complexes with different optical properties: Synthesis, characterization and TD-DFT calculations.
Polyhedron, 144(9), 36-43 (2018)
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