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Sigma-Aldrich

Ruthenium(III) acetylacetonate

97%

Sinónimos:

2,4-Pentanedione ruthenium(III) derivative, Ru(acac)3

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About This Item

Fórmula lineal:
Ru(C5H7O2)3
Número de CAS:
14284-93-6
Peso molecular:
398.39
EC Number:
238-193-0
MDL number:
MFCD00000030
UNSPSC Code:
12352300
PubChem Substance ID:
24857067

Quality Level

100

assay

97%

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

mp

260 °C (dec.) (lit.)

SMILES string

CC(=O)\C=C(\C)O[Ru](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Ru/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

RTZYCRSRNSTRGC-LNTINUHCSA-K

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Categorías relacionadas

Application

A highly active homogeneous catalyst can be formed from ruthenium(III) acetylacetonate during the dehydrogenation of ammonia–borane, which results in the rapid generation of hydrogen gas.It can be used as a catalyst in the hydrolysis of sodium borohydride at low concentrations and room temperature.It can also be used as a precursor to synthesize Ru-based nanomaterials which can be applied in the field of supercapacitors and catalysis.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Yuxiao Zhang et al.
Chemistry, an Asian journal, 14(2), 278-285 (2018-12-07)
Molybdenum disulfide (MoS2 ) has been regarded as a favorable photocatalytic co-catalyst and efficient hydrogen evolution reaction (HER) electrocatalyst alternative to expensive noble-metals catalysts, owing to earth-abundance, proper band gap, high surface area, and fast electron transfer ability. In order
Bih-Show Lou et al.
Scientific reports, 6, 19949-19949 (2016-01-29)
The synthesis of highly dispersed and stable ruthenium nanoparticles (RuNPs; ca. 2-3 nm) on porous activated carbons derived from Moringa Oleifera fruit shells (MOC) is reported and were exploited for supercapacitor applications. The Ru/MOC composites so fabricated using the biowaste carbon
Tuenissen, H.T. Elsevier, C.J.
Chemical Communications (Cambridge, England), 667-667 (1997)
Kaipeng Liu et al.
Nature communications, 11(1), 1263-1263 (2020-03-11)
Single-atom catalysts (SACs) have demonstrated superior catalytic performance in numerous heterogeneous reactions. However, producing thermally stable SACs, especially in a simple and scalable way, remains a formidable challenge. Here, we report the synthesis of Ru SACs from commercial RuO2 powders
Ming Zhao et al.
ACS nano, 13(6), 7241-7251 (2019-05-31)
Owing to their highly open structure and a large number of low-coordination sites on the surface, noble-metal nanoframes are intriguing for catalytic applications. Here, we demonstrate the rational synthesis of Ru cuboctahedral nanoframes with enhanced catalytic performance toward hydrazine decomposition.

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