266841
Iridium
wire, diam. 0.15 mm, 99.9% trace metals basis
Sinónimos:
Iridium black
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About This Item
Fórmula empírica (notación de Hill):
Ir
Número de CAS:
Peso molecular:
192.22
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23
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assay
99.9% trace metals basis
form
wire
resistivity
4.71 μΩ-cm
diam.
0.15 mm
bp
4130 °C (lit.)
mp
2450 °C (lit.)
density
22.65 g/cm3 (lit.)
SMILES string
[Ir]
InChI
1S/Ir
InChI key
GKOZUEZYRPOHIO-UHFFFAOYSA-N
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Quantity
40mg=10cm, 400mg=100cm
Storage Class
13 - Non Combustible Solids
wgk_germany
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
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Enantioselective iridium-catalyzed hydrogenation of 1- and 3-substituted isoquinolinium salts.
Zhi-Shi Ye et al.
Angewandte Chemie (International ed. in English), 52(13), 3685-3689 (2013-02-21)
Daniel Shiu-Hin Chan et al.
PloS one, 8(3), e60114-e60114 (2013-03-28)
We report herein a novel luminescent iridium(III) complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+) ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution). Upon the addition of
Carl W Liskey et al.
Journal of the American Chemical Society, 135(9), 3375-3378 (2013-02-21)
The borylation of cyclopropanes catalyzed by the combination of (η(6)-mes)IrBpin3 or [Ir(COD)OMe]2 and a phenanthroline derivative is reported. The borylation occurs selectively at the methylene C-H bonds of the cyclopropane ring over methine or methyl C-H bonds. High diasteroselectivities were
Yuyang Zhou et al.
Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)
Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
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