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Merck

240761

Sigma-Aldrich

1-Hexene

≥99%

Sinónimos:

1-n-Hexene

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About This Item

Fórmula lineal:
CH3(CH2)3CH=CH2
Número de CAS:
Peso molecular:
84.16
Beilstein/REAXYS Number:
1209240
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

3 (vs air)

Quality Level

vapor pressure

155 mmHg ( 21.1 °C)

assay

≥99%

form

liquid

autoignition temp.

487 °F

refractive index

n20/D 1.388 (lit.)

bp

60-66 °C (lit.)

density

0.678 g/mL at 25 °C (lit.)

SMILES string

CCCCC=C

InChI

1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3

InChI key

LIKMAJRDDDTEIG-UHFFFAOYSA-N

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General description

The kinetics of polymerization of 1-hexene was studied using a family of five zirconium amine bis-phenolate catalysts. Polymerization reaction of 1-hexene catalyzed by a series of hafnium complexes was studied.

Application

  • 1-Hexene in High Molecular Weight Polymer Synthesis: The synthesis of high molecular weight copolymers from 1-hexene and methyl acrylate using Lewis acid catalysts showcased advanced applications in materials science, specifically in developing durable and versatile polymer materials (Wan et al., 2024).
  • 1-Hexene′s Role in Proton-Exchange Membrane Enhancement: Utilizing 1-hexene in the structural characterization and enhancement of physicochemical properties of functionally porous proton-exchange membranes highlights its critical role in improving energy efficiency and performance in fuel cell technologies (Ponomar et al., 2024).

pictograms

FlameHealth hazard

signalword

Danger

hcodes

Hazard Classifications

Asp. Tox. 1 - Flam. Liq. 2

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

-13.0 °F - closed cup

flash_point_c

-25.0 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Takahiro Yasumoto et al.
Dalton transactions (Cambridge, England : 2003), 42(25), 9120-9128 (2012-12-14)
Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
D Keith Steelman et al.
Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
Chia-Hsiu Chen et al.
Journal of the American Chemical Society, 137(21), 6965-6971 (2015-05-12)
The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
Yuichi Ito et al.
Implant dentistry, 24(4), 477-479 (2015-06-04)
The evaluation of bone quality at the site of the alveolar bone for a dental implant is very important. This study presents an easy technique for direct evaluation of alveolar bone quality using nondecalcified cryofilm frozen sections on human alveolar
Astrid-Caroline Knall et al.
Tetrahedron letters, 55(34), 4763-4766 (2014-08-26)
Inverse electron demand Diels-Alder additions (iEDDA) between 1,2,4,5-tetrazines and olefins have recently found widespread application as a novel 'click chemistry' scheme and as a mild technique for the modification of materials. Norbornenes are, due to their straightforward synthetic availability, especially

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