235334
3,6-Dithia-1,8-octanediol
97%
Sinónimos:
2,2′-(Ethylenedithio)diethanol, Lindlar Catalyst Poison
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About This Item
Fórmula lineal:
HO(CH2)2S(CH2)2S(CH2)2OH
Número de CAS:
Peso molecular:
182.30
Beilstein/REAXYS Number:
1739193
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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assay
97%
bp
170 °C/0.5 mmHg (lit.)
mp
63-64 °C (lit.)
functional group
hydroxyl
SMILES string
OCCSCCSCCO
InChI
1S/C6H14O2S2/c7-1-3-9-5-6-10-4-2-8/h7-8H,1-6H2
InChI key
PDHFSBXFZGYBIP-UHFFFAOYSA-N
Categorías relacionadas
General description
3,6-Dithia-1,8-octanediol is a secondary sulfur-based catalyst poison.
Application
3,6-Dithia-1,8-octanediol has been used:
- as exogeneous chelator to evaluate a membrane-permeable copper-selective fluorescent sensor for imaging of kinetically labile copper pools
- in asymmetric total synthesis of (+)-6-epi-castanospermine and polyhydroxylated alkaloid
Storage Class
11 - Combustible Solids
wgk_germany
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Eric J Stoner et al.
The Journal of organic chemistry, 68(23), 8847-8852 (2003-11-08)
Functionalized erythromycin 9-oxime derivatives are 6-O-allylated under mild conditions using substituted allyl tert-butyl carbonates under palladium(0) catalysis. This allylation works well where traditional ether-forming protocols function poorly. Allyl tert-butyl carbonates provide higher yields in this reaction than lesser substituted carbonates
Asymmetric Total Synthesis of (+)-6-epi-Castanospermine by the Stereoselective Formation of a syn, anti Acetylenic 2-Amino-1, 3-diol Stereotriad.
Louvel J, et al.
European Journal of Organic Chemistry, 2010(15), 2921-2926 (2010)
Liuchun Yang et al.
Proceedings of the National Academy of Sciences of the United States of America, 102(32), 11179-11184 (2005-08-03)
Copper is an essential micronutrient that plays a central role for a broad range of biological processes. Although there is compelling evidence that the intracellular milieu does not contain any free copper ions, the rapid kinetics of copper uptake and
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