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Merck
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Key Documents

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229237

Sigma-Aldrich

4,4′-Dibromobiphenyl

98%

Sinónimos:

1-Bromo-4-(4-bromophenyl)benzene, 4,4′-Dibromo-1,1′-biphenyl, 4,4′-Dibromodiphenyl, 4′,4-Dibromobiphenyl, PBB 15, p,p′-Dibromobiphenyl

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About This Item

Fórmula lineal:
BrC6H4C6H4Br
Número de CAS:
92-86-4
Peso molecular:
312.00
Beilstein/REAXYS Number:
2044701
EC Number:
202-198-6
MDL number:
MFCD00000101
UNSPSC Code:
12352100
PubChem Substance ID:
24853738
NACRES:
NA.22

assay

98%

form

solid

bp

355-360 °C (lit.)

mp

163-165 °C (lit.)

SMILES string

Brc1ccc(cc1)-c2ccc(Br)cc2

InChI

1S/C12H8Br2/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10/h1-8H

InChI key

HQJQYILBCQPYBI-UHFFFAOYSA-N

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Categorías relacionadas

General description

The degradation of 4,4′-dibromobiphenyl, through photoelectrocatalytic process, was studied.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Marola M H van Lipzig et al.
Chemical research in toxicology, 18(11), 1691-1700 (2005-11-23)
Exposure of humans and wildlife to xenobiotics, such as halogenated biphenyls, that interfere with the endogenous estrogen balance may lead to endocrine disruption. Such compounds may either mimic or block estradiol's action by agonistic or antagonistic action, respectively. They may
Jinyang Chen et al.
Journal of hazardous materials, 235-236, 85-91 (2012-07-31)
In situ transformation of 4,4'-Dibromobiphenyl (4,4'-DBB) in water was observed with hydrothermal diamond anvil cell (HDAC) up to 633 K. It shows that 4,4'-DBB dissolves in water to form a homogenous phase at the temperature of 588 K and thus
Sierra Rayne et al.
Water research, 37(3), 551-560 (2003-04-12)
The anaerobic microbial and photochemical degradation pathways of 4,4'-dibromodiphenyl ether (BDE15) were examined. BDE15 was reductively debrominated within a fixed-film plug-flow biological reactor at hydraulic retention times of 3.4 and 6.8 h, leading to exclusive production of 4-bromodiphenyl ether (BDE3)
Haijin Liu et al.
Chemosphere, 82(1), 43-47 (2010-11-03)
Polybrominated biphenyls have been widely used as flameretardants in textile and electronic industries, and additives in plastics. Over the past few decades, much attention has been given to polybrominated biphenyls in the environment and their effects on humans. In this
Shanshan Qiu et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(5), 429-434 (2010-05-11)
In this work, both experimental and theoretical study on the FT-IR and Raman spectra as well as (1)H NMR and (13)C NMR chemical shifts of 4,4'-dibromodiphenyl ether have been carried out. The optimized geometry was obtained by using both HF
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