Saltar al contenido
Merck
Todas las fotos(5)

Key Documents

View All Documentation

213217

Sigma-Aldrich

Lithium amide

greener alternative

powder, 95%

Sinónimos:

Aminolithium, Lithamide

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(5)

About This Item

Fórmula lineal:
LiNH2
Número de CAS:
7782-89-0
Peso molecular:
22.96
EC Number:
231-968-4
MDL number:
MFCD00011093
UNSPSC Code:
12352301
PubChem Substance ID:
24852671
NACRES:
NA.22

Quality Level

200

assay

95%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

380-400 °C

density

1.178 g/mL at 25 °C (lit.)

greener alternative category

Enabling,

SMILES string

[Li].CN

InChI

1S/Li.H2N/h;1H2/q+1;-1

InChI key

AFRJJFRNGGLMDW-UHFFFAOYSA-N

¿Está buscando productos similares? Visita Guía de comparación de productos

Categorías relacionadas

General description

Lithium amide (LiNH2) is an amide of an alkali metal with lithium atoms having larger positive charges than hydrogen atoms. It is a moisture-sensitive molecule that converts to LiOH and NH3 on reaction with H2O. LiNH2 is majorly used in hydrogen storage applications.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Reagent for synthesis of:
Antiinflamatory and preoresolving protectin D1
Chemotype dipeptidyl peptidase IV inhibitors
Sterically congested triarylamines
Dyes displaying large Stokes shifts
GM1 ganglioside derivatives

Reagent for cross-coupling of aryl chlorides and amines

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

hcodes

H261,H314

Hazard Classifications

Skin Corr. 1B - Water-react 2

supp_hazards

EUH014,EUH029

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Elija entre una de las versiones más recientes:

Certificados de análisis (COA)

Lot/Batch Number
MKCQ1601
MKCP6355
MKCP4040
MKCN1643
MKCK1837

¿No ve la versión correcta?

Si necesita una versión concreta, puede buscar un certificado específico por el número de lote.

Busque por un COA

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Yukihiro Nishio et al.
Bioorganic & medicinal chemistry letters, 20(24), 7246-7249 (2010-11-16)
Structures containing the (R)-3-amino-3-methyl piperidine unit as a new pharmacophore moiety have been shown to possess moderate inhibitory activity for DPP-4 with good pharmacokinetics profile. One of these compounds was found to have good oral bioavailability and PK/PD profile in
N. Ogawa and Y. Kobayashi,
Tetrahedron Letters, 52, 3001-3004 (2011)
G. Bordeau, et al.,
Tetrahedron Letters, 51, 4429-4432 (2010)
R. Kuwano, et al.,
Synlett, 12, 1819-1824 (2010)
Rylan J Lundgren et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(6), 1983-1991 (2009-12-22)
The syntheses of 2-(di-tert-butylphosphino)-N,N-dimethylaniline (L1, 71%) and 2-(di-1-adamantylphosphino)-N,N-dimethylaniline (L2, 74 %), and their application in Buchwald-Hartwig amination, are reported. In combination with [Pd(allyl)Cl](2) or [Pd(cinnamyl)Cl](2), these structurally simple and air-stable P,N ligands enable the cross-coupling of aryl and heteroaryl chlorides
Ver todos los artículos relacionados

Artículos

Complex Hydrides: A New Category of Solid-state Lithium Fast-ion Conductors

Research and development of solid-state lithium fast-ion conductors is crucial because they can be potentially used as solid electrolytes in all-solid-state batteries, which may solve the safety and energy-density related issues of conventional lithium-ion batteries that use liquid (farmable organic) electrolytes.

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico