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Merck
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146617

Sigma-Aldrich

Bathophenanthrolinedisulfonic acid disodium salt hydrate

98%

Sinónimos:

Bathophenanthrolinedisulfonic acid disodium hydrate

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About This Item

Fórmula empírica (notación de Hill):
C24H14N2Na2O6S2 · 3H2O
Número de CAS:
52746-49-3
Peso molecular:
590.53
EC Number:
258-152-0
UNSPSC Code:
12352100
NACRES:
NA.22

Quality Level

100

assay

98%

form

powder

mp

300 °C

solubility

water: soluble 100 mg/mL, clear to slightly hazy, yellow (to red)

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General description

Bathophenanthrolinedisulfonic acid disodium salt forms water soluble complexes with palladium and their catalytic role in oxidation of 2-hexanol has been examined.

Application

Bathophenanthrolinedisulfonic acid disodium salt hydrate was used in the preparation of anionic Europium(III) disulfonated bathophenanthroline tris(dibenzoylmethanate) complex.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Intercalation of luminescent Europium (III) complexes in layered double hydroxides.
Sarakha L, et al.
Opt. Mater., 31(3), 562-566 (2009)
Catalytic Conversions in Water. Part 23: Steric Effects and Increased Substrate Scope in the Palladium-Neocuproine Catalyzed Aerobic Oxidation of Alcohols in Aqueous Solvents#.
Brink GJ, et al.
Advanced Synthesis & Catalysis, 345(12), 1341-1352 (2003)
A Paolicchi et al.
Journal of investigative medicine : the official publication of the American Federation for Clinical Research, 47(3), 151-160 (1999-04-13)
gamma-Glutamyl transpeptidase (gamma-GT) is found in serum and in the plasma membranes of virtually all cell types. Its physiologic role is to initiate the hydrolysis of extracellular glutathione (GSH), a tripeptide in which cysteine lies between alpha-glycine and gamma-glutamate residues.
Simone Zanarini et al.
The journal of physical chemistry. B, 112(33), 10188-10193 (2008-07-26)
In this work, the electrochemical and ECL properties of tris[1,10-phenanthrolinediyl-4,7-di(benzenesulfonate)]Ru(II) ([Ru(BPS)3]4-) have been addressed in both strictly aprotic conditions and aqueous buffers. A combined theoretical and experimental approach is presented to focus thermodynamics and kinetic effects of electro-generated species possessing
J M May et al.
Biochemical pharmacology, 57(11), 1275-1282 (1999-05-07)
The role of ascorbic acid in transferrin-independent ferric iron reduction and uptake was evaluated in cultured U-937 monocytic cells. Uptake of 55Fe by U-937 cells was doubled by 100 microM extracellular ascorbate, and by pre-incubation of cells with 100 microM
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