341622
Bromopentacarbonylmanganese(I)
98%
Synonym(s):
Bromopentacarbonylmanganese(I), Manganese pentacarbonyl bromide
About This Item
Recommended Products
Quality Level
Assay
98%
form
powder or crystals
reaction suitability
core: manganese
reagent type: catalyst
storage temp.
2-8°C
SMILES string
[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key
OESORJHGSXJTKX-UHFFFAOYSA-M
Application
- A precursor to synthesize manganese complex, [Mn(CO)5H], which was then used as a catalyst in the reduction of levulinic acid (LA) to methyltetrahydrofuran (MTHF) and the reductive amination of LA to N-substituted pyrrolidines.
- A precursor to prepare Mn(I) complexes bearing bifunctional ligands, which are used as catalysts for the transfer-hydrogenation of various ketones and imines using 2-propanol as the hydrogen donor.
- A catalyst in the selective C2-H activation reactions.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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