271349

5-Hexynenitrile

97%

• Synonym(s): 5-Cyano-1-pentyne
• Linear Formula: HC≡C(CH₂)₃CN
• CAS Number: 14918-21-9
• Molecular Weight: 93.13
• Beilstein: 1735926
• MDL number: MFCD00001978
• UNSPSC Code: 12352100
• PubChem Substance ID: 24856432
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 97%
• form: liquid
• refractive index: n20/D 1.44 (lit.)
• bp: 115-117 °C (lit.)
• density: 0.889 g/mL at 25 °C (lit.)
• functional group: nitrile
• storage temp.: 2-8°C
• SMILES string: C#CCCCC#N
• InChI: 1S/C6H7N/c1-2-3-4-5-6-7/h1H,3-5H2
• InChI key: JZYKFLLRVPPISG-UHFFFAOYSA-N

Description

Application

5-Hexynenitrile was used in the synthesis of annelated symmetric and asymmetric 3,3′-disubstituted 2,2′-bipyridines by cobalt(I)-catalyzed [2+2+2] cycloadditions with 1,3-diynes.

Safety Information

• Pictograms: GHS02,GHS07
• Signal Word: Warning
• Hazard Statements: H226,H302 + H312 + H332,H315,H319,H335
• Precautionary Statements: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 107.6 °F - closed cup
• Flash Point(C): 42 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves