213403

N-Selectride^®

1.0 M in THF

• Synonym(s): Sodium tri-sec-butylborohydride solution
• Linear Formula: NaB[CH(CH₃)C₂H₅]₃H
• CAS Number: 67276-04-4
• Molecular Weight: 206.15
• MDL number: MFCD00011709
• UNSPSC Code: 12352001
• PubChem Substance ID: 24852780
• NACRES: NA.22

Properties

• form: liquid
• reaction suitability: reagent type: reductant
• concentration: 1.0 M in THF
• density: 0.893 g/mL at 25 °C (lit.)
• SMILES string: [Na+].CCC(C)[BH-](C(C)CC)C(C)CC
• InChI: 1S/C12H28B.Na/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
• InChI key: JUFGMKFPFVIKOY-UHFFFAOYSA-N

Description

Application

• Reducing agent

Reactant for:

• Conjugate hydride reduction-initiated tandem cyclization reactions
• Sereoselective nucleophilic addition reactions

Legal Information

Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H260,H302,H314,H335,H351
• Precautionary Statements: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Target Organs: Respiratory system
• Supplementary Hazards: EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 5.0 °F - closed cup
• Flash Point(C): -15 °C - closed cup