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Merck

741035

Sigma-Aldrich

2-十二烷基硫代羰基硫代-2-甲基丙酸N-羟基琥珀酰亚胺酯

98% (HPLC)

别名:

N-羟基琥珀酰亚胺2-(十二烷基硫基硫代羰基硫基)异丁酸酯

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About This Item

经验公式(希尔记法):
C21H35NO4S3
分子量:
461.70
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

98% (HPLC)

形狀

solid

mp

96-102 °C

儲存溫度

2-8°C

SMILES 字串

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)ON1C(=O)CCC1=O

InChI

1S/C21H35NO4S3/c1-4-5-6-7-8-9-10-11-12-13-16-28-20(27)29-21(2,3)19(25)26-22-17(23)14-15-18(22)24/h4-16H2,1-3H3

InChI 密鑰

HKWLQDYVQCZTQP-UHFFFAOYSA-N

一般說明

需要帮助选择正确的RAFT试剂?请查阅RAFT试剂与单体的相容性表

應用

用于受控自由基聚合的官能化RAFT试剂,特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。NHS酯末端可用于与多种生物分子偶联。链转移剂(CTA)。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

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实验方案

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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