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323446

Sigma-Aldrich

Ammonium tetrathiomolybdate

99.97% trace metals basis

Synonym(s):

Ammonium thiomolybdate, Diammonium tetrathiomolybdate

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About This Item

Linear Formula:
(NH4)2MoS4
CAS Number:
15060-55-6
Molecular Weight:
260.28
MDL number:
MFCD00136013
UNSPSC Code:
12352302
PubChem Substance ID:
24859366
NACRES:
NA.23
form:
crystalline

Quality Level

100

Assay

99.97% trace metals basis

form

crystalline

reaction suitability

reagent type: catalyst
core: molybdenum

impurities

≤350.0 ppm Trace Metal Analysis

mp

>300 °C (lit.)

SMILES string

[NH4+].[NH4+].[S-][Mo]([S-])(=S)=S

InChI

1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2

InChI key

PQNOIAHNKHBLRN-UHFFFAOYSA-P

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Application

Ring opening of aziridines leading to sulfides and disulfides.
This classic building block for transition metal sulfide cluster compounds was recently used in a low-temperature, solid state synthesis of a new series of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands.

Biochem/physiol Actions

Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ4519
MKCM4844
MKCK3064
MKCJ8657
MKCG8991

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Satoru Yamasaki et al.
The Journal of cell biology, 177(4), 637-645 (2007-05-16)
Zinc is an essential trace element required for enzymatic activity and for maintaining the conformation of many transcription factors; thus, zinc homeostasis is tightly regulated. Although zinc affects several signaling molecules and may act as a neurotransmitter, it remains unknown
George J Brewer
Current cancer drug targets, 5(3), 195-202 (2005-05-17)
Tetrathiomolybdate (TM) is a novel anticopper agent under development for use in Wilson's disease. It acts by forming a stable tripartite complex with serum albumin and copper, rendering the complexed copper unavailable for cellular uptake. TM is a very potent
Yu Cheng et al.
Molecular pharmaceutics, 16(8), 3489-3501 (2019-06-28)
Recently, multifunctional clearable inorganic theranostic nanoparticles have been attracting more and more attention. Protein-based nanoparticles can be cleared by the hepatobiliary system efficiently. In this work, ultrasmall gadolinium oxide (Gd2O3) nanoparticles, which possess the advantage of high longitudinal relaxation rate
Devarajulu Sureshkumar et al.
The Journal of organic chemistry, 72(6), 2106-2117 (2007-02-24)
A comprehensive study of a general and effective one-step procedure for the synthesis of beta-sulfonamidodisulfides directly from N-tosyl aziridines in a regio- and stereospecific manner under neutral conditions without the use of any Lewis acid or base has been reported.
Lang, J-P. Tatsumi, K.
Inorganic Chemistry, 37, 6308-6308 (1998)
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