Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Molecules (Basel, Switzerland) (2013-05-28)

Jana Doháňošová, Tibor Gracza

ABSTRACT

The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.

MATERIALS

Product Number

Brand

Product Description

GF57528816

Palladium, foil, not light tested, 25x25mm, thickness 0.006mm, 99.95%

GF55924241

Palladium, foil, not light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%

GF44874995

Palladium, foil, light tested, 100x100mm, thickness 0.047mm, as rolled, 99.95%

GF94632576

Palladium, foil, light tested, 100x100mm, thickness 0.075mm, as rolled, 99.95%

GF74894136

Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.95%

GF60234533

Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.99+%

GF69074916

Palladium, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.75%

GF55245821

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

GF70629880

Palladium, foil, not light tested, 50x50mm, thickness 0.003mm, 99.95%

GF90054659

Palladium, rod, 50mm, diameter 6.0mm, 99.95%

GF75251909

Palladium, microfoil, disks, 10mm, thinness 0.05μm, specific density 63.6μg/cm², permanent mylar 3.5μm support, 99.99%

GF51599425

Palladium, foil, not light tested, 100x100mm, thickness 0.004mm, 99.95%

GF96040111

Palladium, foil, not light tested, 50x50mm, thickness 0.004mm, 99.95%

GF50988358

Palladium, foil, light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%

GF88744843

Palladium, wire reel, 1m, diameter 0.02mm, as drawn, 99.95%

GF42154051

Palladium, foil, light tested, 50x50mm, thickness 0.025mm, as rolled, 99.99+%

GF28406235

Palladium, microfoil, disks, 10mm, thinness 0.1μm, specific density 119.2μg/cm², permanent mylar 3.5μm support, 99.99%

GF73143491

Palladium, foil, not light tested, 25x25mm, thickness 0.0125mm, 99.95%

GF62759841

Palladium, foil, not light tested, 100x100mm, thickness 0.005mm, 99.95%

GF84888297

Palladium, microfoil, disks, 25mm, thinness 0.25μm, specific density 303.4μg/cm², permanent mylar 3.5μm support, 99.99%

GF31401627

Palladium, foil, not light tested, 50x50mm, thickness 0.001mm, permanent polyester support, 99.75%

GF81435146

Palladium, rod, 100mm, diameter 2.0mm, 99.95%

GF68272588

Palladium, rod, 25mm, diameter 6.0mm, 99.95%

GF48230197

Palladium, foil, not light tested, 50x50mm, thickness 0.025mm, as rolled, 99.99+%

GF16402586

Palladium, foil, not light tested, 25x25mm, thickness 0.002mm, 99.95%

GF36936399

Palladium, foil, light tested, 50x50mm, thickness 0.03mm, as rolled, 99.95%

GF35196330

Palladium, tube, 100mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%

GF71674612

Palladium, foil, not light tested, 50x50mm, thickness 0.006mm, 99.95%

GF23340709

Palladium, foil, not light tested, 25x25mm, thickness 0.0005mm, 99.75%

GF21222447

Palladium, foil, not light tested, 50x50mm, thickness 0.02mm, as rolled, 99.95%