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683159

Sigma-Aldrich

Chiralyst P468

Umicore

Synonym(s):

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, Bis(1,5-cyclooctadiene)rhodium triflate

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About This Item

Empirical Formula (Hill Notation):
C17H24F3O3RhS
CAS Number:
Molecular Weight:
468.34
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

powder

reaction suitability

core: rhodium
reagent type: catalyst

mp

159 °C (dec. literature value) (lit.)
83-97 °C (dec. experimental value)

SMILES string

[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b2*2-1-,8-7-;;

InChI key

GOPBTCMAUMSOBX-QMDOQEJBSA-M

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Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Articles

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions. 20 different precatalyst complexes are available, providing access to hundred different catalytic reactions.

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